Thorium Fluoride SDS
SDS of Thorium Fluoride
SAFETY DATA SHEET
- Identification
Product identifier Thorium Fluoride
Synonyms Thorium tetrafluoride
Manufacturer
Company name International Bio-Analytical Industries, Inc.
Address 3495 N. Dixie Hwy. Unit 8
Boca Raton, Florida
33487
United States
Telephone 561-826-0061
E-mail contact@ibilabs.com
- Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
Label elements


Signal word Warning
Hazard statement
Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. May cause
harm to breast-fed children. May cause damage to organs through prolonged or repeated exposure.
Suspected of damaging fertility or the unborn child.
Precautionary statement
Prevention
Do not handle until all safety precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. Wash thoroughly
after handling. Do not eat, drink or smoke when using this product. Wear eye protection/face
protection. Wear protective gloves. Use personal protective equipment as required. Observe good
industrial hygiene practices.
Response
If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get
medical assistance if you feel unwell. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get
medical advice/attention. Call a poison center/doctor if you feel unwell. If skin irritation occurs: Get
medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off
contaminated clothing and wash before reuse. Wash hands after handling.
Storage
Store in a well-ventilated place. Keep container tightly closed. Store away from incompatible materials.
Disposal
Dispose of waste and residues in accordance with local authority requirements. Dispose of
contents/container (in accordance with related regulations).
Hazard(s) not otherwise classified (HNOC)
Radioactive.
Radioactive material must be handled by qualified personnel in conformity with
regulations appropriate to the government agency authorized to license the use of this
radionuclide.
- Composition/information on ingredients
Substances
Chemical name Common name and synonyms CAS number %
Thorium Fluoride Thorium tetrafluoride 13709-59-6100 100
- First-aid measures
Inhalation
Move to fresh air. Notify radiation safety personnel immediately. Call a physician if symptoms
develop or persist. The amount of material inhaled should be assessed and documented.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Do not abrade
skin. Always blot dry. Notify radiation safety personnel. Get medical attention if irritation develops
and persists.
Eye contact
Rinse with water. Remove contact lenses, if present and easy to do. Notify radiation safety
personnel. Get medical attention if irritation develops and persists.
Ingestion
Notify radiation safety personnel immediately. Rinse mouth. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation.
Indication of immediate medical attention and special treatment needed
Treat symptomatically.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
- Fire-fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire. Use fire-extinguishing media appropriate for surrounding materials.
Specific hazards arising from the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment and precautions for firefighters
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask.
Fire fighting equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards
No unusual fire or explosion hazards noted.
- Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Avoid contact with spilled material. For personal protection, see section 8 of the SDS.
Methods and materials for containment and cleaning
Collect and dispose of spillage as indicated in section 13 of the SDS. In the event of a spill or
upaccidental release, notify relevant authorities in accordance with all applicable regulations. Clean
up in accordance with all applicable regulations. Stop the flow of material, if this is without risk.
Following product recovery, flush area with water.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
- Handling and storage
Precautions for safe handling
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Avoid all personal contact. Avoid contact with skin. Avoid contact with eyes. Avoid
contact during pregnancy/while nursing. Avoid prolonged exposure. When using, do not eat, drink
or smoke. Use personal protective equipment as required. Wash thoroughly after handling. Avoid
release to the environment.
Conditions for safe storage, including any incompatibilities
Store locked up. Store in a place accessible by authorized persons only. Store in a cool, dry place
out of direct sunlight. Store in original tightly closed container. Keep container tightly closed. Keep
out of the reach of children. Store away from incompatible materials (see Section 10 of the SDS).
Store in accordance with local/regional/national/international regulation.
- Exposure controls/personal protection
Occupational exposure limits
US OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Material Type Value
————————————————————————————————————————————————————————————————————————————–
Thorium Fluoride (CAS 13709-59-6) PEL 2.5 mg/m3
US OSHA Table Z-2 (29 CFR 1910.1000)
Material Type Value Form
————————————————————————————————————————————————————————————————————————————–
Thorium Fluoride (CAS 13709-59-6) TWA 2.5 mg/m3 Dust.
US ACGIH Threshold Limit Values
————————————————————————————————————————————————————————————————————————————–
Material Type Value
————————————————————————————————————————————————————————————————————————————–
Thorium Fluoride (CAS 13709-59-6) TWA 2.5 mg/m3
US NIOSH: Pocket Guide to Chemical Hazards
Material Type Value
————————————————————————————————————————————————————————————————————————————–
Thorium Fluoride (CAS 13709-59-6) TWA 2.5 mg/m3
California Code of Regulations, Title 8, Section 5155. Airborne Contaminants
Material Type Value
————————————————————————————————————————————————————————————————————————————–
Thorium Fluoride (CAS 13709-59-6) PEL 2.5 mg/m3
Biological limit values
ACGIH Biological Exposure Indices
Material Value Determinant Specimen Sampling Time
Thorium Fluoride (CAS 13709-59-6) 3 mg/l Fluoride Urine *
2 mg/ lFluoride Urine *
* – For sampling details, please see the source document.
Control parameters Follow standard monitoring procedures. Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. Rubber gloves. Suitable gloves can be recommended by the glove supplier.
Other
Wear suitable protective clothing. Lab coat.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
No smoking, eating or drinking should be allowed in any area where radioactive materials are
handled or stored. When using, do not eat, drink or smoke. Always observe good personal
hygiene measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
- Physical and chemical properties
Appearance
Physical state Solid.
Form Solid.
Color Not available.
Odor Not applicable.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling range Not applicable.
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit – lower (%) Not available.
Flammability limit – upper (%) Not available.
Explosive limit – lower (%) Not available.
Explosive limit – upper (%) Not available.
Vapor pressure < 0.0000001 kPa at 25 °C
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient (n-octanol/water) Not available.
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Molecular formula F4Th
Oxidizing properties Not oxidizing.
- Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Stable; however, may decompose if heated.
Possibility of hazardous reactions No dangerous reaction known under conditions of normal use.
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition products No hazardous decomposition products are known.
- Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Due to lack of data the classification is not possible.
Symptoms related to the physical, chemical and toxicological characteristics Irritant effects.
Information on toxicological effects
Acute toxicity May cause respiratory irritation.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye irritation Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitization Due to lack of data the classification is not possible.
Skin sensitization Due to lack of data the classification is not possible.
Germ cell mutagenicity Due to lack of data the classification is not possible.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Thorium Fluoride (CAS 13709-59-6) Not classifiable as to carcinogenicity to humans US OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity May cause harm to breastfed babies. Suspected of damaging fertility or the unborn child.
Specific target organ toxicity single exposure Respiratory tract irritation.
Specific target organ toxicity – repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard Due to lack of data the classification is not possible.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful.
Further information This product has no known adverse effect on human health.
- Ecological information
Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
- Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Radioactive waste must be handled in accordance with procedures established by your Radiation Safety Officer, NRC and other applicable regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues / unused products Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Dispose of in accordance with local regulations.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
- Transport information
The U.S. Department of Transportation (D.O.T.) Code of Federal Regulations (49 CFR Parts 100-185), the International Air Transportation Association (IATA), International Civil Aviation Organization (ICAO) and International Maritime Organization (IMDG) are all factored into the classification and transport of material.
Proper Shipping Name: To be determined on a case by case basis.
Hazard Class: To be determined on a case by case basis.
UN/ID Number: To be determined on a case by case basis.
Special Information: To be determined on a case by case basis.
Packing Group: To be determined on a case by case basis.
Classification of substances with multiple hazards must be determined in accordance with the criteria presented in the above mentioned regulations. Due to the various quantities/combinations of materials being shipped at one time, the information above must be determined based on the characteristics of the specific shipment.
- Regulatory information
US federal regulations CERCLA/SARA Hazardous Substances – Not applicable.
All components are on the U.S. EPA TSCA Inventory List.
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed
US OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard – No
Delayed Hazard – No
Fire Hazard – No
Pressure Hazard – No
Reactivity Hazard – No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 HazardousYes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act4.0 mg/l
(SDWA)4.0 mg/l
US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US – New Jersey RTK – Substances: Listed substance
Thorium Fluoride (CAS 13709-59-6)
- California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
- Massachusetts RTK – Substance List
Not regulated.
- New Jersey Worker and Community Right-to-Know Act
Not regulated.
- Pennsylvania RTK – Hazardous Substances
Thorium Fluoride (CAS 13709-59-6)
- Pennsylvania Worker and Community Right-to-Know Law
Thorium Fluoride (CAS 13709-59-6)
- Rhode Island RTK
Not regulated.
- California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
- Other information, including date of preparation or last revision
Revision date 02-01-2016
Version #1
Further informationEmergency telephone numbers
Austria – VergiftungsInformationsZentrale, +431.406.43.43
Belgium – Centre Antipoisons – +070.245.245
Bulgaria – Телефон за спешни случаи / факс, +359.2.9154.409
Cyprus – +357.22405611
Czech Republic – Toxikologické informační středisko, +420.224.919.293
Denmark – Akuthjælp ved forgiftning, +82.12.12.12
Estonia – Mürgistusteabekeskuse, 16662
Finland – Myrkytystietokeskus, +(0)9.471.977
France – numéro ORFILA, +33.(0)1.45.42.59.59
Germany – GIZ-Nord Poisons Centre, +49.(0)551.383.1876
Greece – +30.210.64.79.286
Hungary – Az Egészségügyi Toxikológiai Tájékoztató Szolgálat, +36 1 476 6464
Iceland – +354.591.2000
Ireland – National Poisons Information Centre – +353.01.8092566
Italy – Istituto Superiore di Sanità, 064990.2423
Latvia – Valsts Toksikoloģijas centra Saindēšanās un zāļu informācijas centrs, +371.67042473
Liechtenstein – +423.236.61.95
Lithuania – Neatidėliotina informacija apsinuodijus, +370 5 236 20 52
Luxembourg – +352 42 59 91 600
Malta – 2545 0000
Netherlands – NVIC, 030-2748888
Norway – Giftinformasjonen, 22.59.13.00
Poland – Biuro ds. Substancji Chemicznych, +48 42 2538 424
Portugal – 808.250.143
Romania – Biroul RSI si Informare Toxicologica, 021.318.36.06
Slovakia – NTIC, +421.2.5477.4166
Slovenia – Kemična urad Republike Slovenije + 386.14.00.60.51
Spain – Servicio de Información Toxicológica, + 34.91.562.04.20
Sweden – 112
ReferencesACGIH
EPA: AQUIRE database
NLM: Hazardous Substances Data Base
- IARC Monographs on Occupational Exposures to Chemical Agents
DisclaimerAdditional information is given in the Material Safety Data Sheet. IBI Labs cannot
anticipate all conditions under which this information and its product, or the products of other
manufacturers in combination with its product, may be used. It is the user’s responsibility to
ensure safe conditions for handling, storage and disposal of the product, and to assume liability for
loss, injury, damage or expense due to improper use.
This document has been prepared using data from sources considered to be technically reliable
and the information is believed to be correct. IBI Labs makes no warranties, expressed or implied,
as to the accuracy of the information contained herein. Materion cannot anticipate all conditions
under which this information and its products may be used and the actual conditions of use are
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