SAFETY DATA SHEET
Version 4.4
Revision Date 06/25/2014
Print Date 12/19/2014
- PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name : Uranyl Chloride Hydrated
Product Number :
Brand : IBI Labs
Index-No. :
CAS-No. : 13867-67-9
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company IBI Labs
3495 N. Dixie Hwy. Unit # 8
Boca Raton, FL 33431
USA
Telephone : +1 561-826-0061
Fax : +1 561-892-8450
1.4 Emergency telephone number
Emergency Phone # : (561) 826-0061
- HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 2), H300
Acute toxicity, Inhalation (Category 2), H330
Specific target organ toxicity – repeated exposure (Category 2), H373
Acute aquatic toxicity (Category 2), H401
Chronic aquatic toxicity (Category 2), H411
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word Danger
Hazard statement(s)
H300 + H330 Fatal if swallowed or if inhaled
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P284 Wear respiratory protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P320 Specific treatment is urgent (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
Radioactive.
- COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Formula : UO2Cl2*3H2O
Molecular Weight : 394.979
CAS-No. : 13867-67-9
EC-No. :
Index-No. :
Component Classification Concentration
Uranyl Chloride Hydrated
Acute Tox. 2; STOT RE 2;
Aquatic Acute 2; Aquatic
Chronic 2; H300 + H330, H373, H411
For the full text of the H-Statements mentioned in this Section, see Section 16.
- FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
- FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Chlorides, Uranium oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
- ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
- HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
- EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters
Component CAS-No. Value Control parameters
Uranyl Chloride
TWA 0.2 mg/m3 USA. ACGIH Threshold Limit Values (TLV)
Remarks Confirmed human carcinogen
TWA 0.05 mg/m3 USA. Occupational Exposure Limits
(OSHA) – Table Z-1 Limits for Air Contaminants
TWA 0.05 ppm
USA. OSHA – TABLE Z-1 Limits for Air Contaminants – 1910.1000
STEL 0.6 mg/m3 USA. ACGIH Threshold Limit Values (TLV)
Confirmed human carcinogen
TWA 0.05 mg/m3 USA. Occupational Exposure Limits
(OSHA) – Table Z-1 Limits for Air Contaminants
TWA 0.05 mg/m3 USA. OSHA – TABLE Z-1 Limits for Air Contaminants – 1910.1000
TWA 0.05 mg/m3 USA. NIOSH Recommended Exposure Limits
Potential Occupational Carcinogen
See Appendix A
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
- PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
- a) Appearance Form: crystalline Colour: yellow crystalline
- b) Odour no data available
- c) Odour Threshold no data available
- d) pH no data available
- e) Melting point/freezing point no data available
- f) Initial boiling point and boiling range no data available
- g) Flash point no data available
- h) Evapouration rate no data available
- i) Flammability (solid, gas) no data available
- j) Upper/lower flammability or explosive limits no data available
- k) Vapour pressure no data available
- l) Vapour density no data available
- m) Relative density
- n) Water solubility no data available
- o) Partition coefficient: noctanol/water no data available
- p) Auto-ignition temperature no data available
- q) Decomposition temperature
- r) Viscosity no data available
- s) Explosive properties no data available
- t) Oxidizing properties no data available
9.2 Other safety information
no data available
- STABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products – no data available
In the event of fire: see section 5
- TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral – rat – 204 mg/kg
Remarks: Behavioral:Tremor. Skin and Appendages: Other: Hair. Nutritional and Gross Metabolic:Changes in:Body temperature decrease.
Dermal: no data available
LD50 Subcutaneous – rat – 8.300 mg/kg
Remarks: Behavioral:Tremor. Skin and Appendages: Other: Hair. Nutritional and Gross Metabolic:Changes in:Body temperature decrease.
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Contains a radioactive isotope which may produce cancer and genetic mutation.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity – single exposure
no data available
Specific target organ toxicity – repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Additional Information
RTECS: Not available
Conjunctivitis., Blood disorders, Symptoms may be delayed., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
- ECOLOGICAL INFORMATION
12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.
no data available
- DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
- TRANSPORT INFORMATION
DOT (US)
UN number: 2910
Proper shipping name: Toxic solid, inorganic, n.o.s. (uranyl chloride)
Reportable Quantity (RQ): 100 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2910 EMS-No: F-A, S-A
Proper shipping name: TOXIC SOLID, INORGANIC, N.O.S. (uranyl chloride)
Marine pollutant: Marine pollutant
IATA
UN number: 2910
Proper shipping name: Toxic solid, inorganic, n.o.s. (uranyl chloride)
Further information
Radioactive material, excepted package – limited quantity of material
- REGULATORY INFORMATION
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Uranyl Chloride Hydrated
CAS-No. 13867-67-9
Revision Date
1993-04-24
Pennsylvania Right To Know Components
CAS-No. Revision Date
uranyl chloride Hydrated
New Jersey Right To Know Components
uranyl chloride hydrated
CAS-No. 13867-67-9
Revision Date
1993-04-24
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
- OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox. Acute toxicity
Aquatic Acute Acute aquatic toxicity
Aquatic Chronic Chronic aquatic toxicity
H300 Fatal if swallowed.
H300 + H330 Fatal if swallowed or if inhaled
H330 Fatal if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H401 Toxic to aquatic life.
HMIS Rating
Health hazard: 3
Chronic Health Hazard: *
Flammability: 0
Physical Hazard 0
NFPA Rating
Health hazard: 4
Fire Hazard: 0
Reactivity Hazard: 0
Further information
Copyright 2014 IBI Labs. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. IBI Labs and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product
Preparation Information
IBI Labs
Product Safety – Americas Region
1-561-826-0061
Version: 4.4 Revision Date: 06/25/2014 Print Date: 12/19/2014