Uranyl Oxalate Trihydrate SDS

1. IDENTIFICATION

Trade name: Uranyl Oxalate Trihydrate

Synonyms: Uranyl Oxalate

Formula: UO2C2O4·3H2O

CAS RN: [2031-89-2]

Relevant identified uses of the substance or mixture and uses advised against: No further relevant information available.

Application of the substance and the preparation: Laboratory chemicals.

Supplier

IBI Labs

3495 N. Dixie Hwy. Unit # 8

Boca Raton, FL 33431

Tel: 561-826-0061 Fax: 561-892-8450

Emergency Telephone Numbers

INFOTRAC

USA & Canada contact number: 1-800-535-5053

International contact number: 1-352-323-3500

2. HAZARDS IDENTIFICATION

Classification of The Substance or Mixture

GHS06 Skull and crossbones

H301 Toxic if swallowed.

H331 Toxic if inhaled.

GHS07

H312 Harmful in contact with skin.

H319 Causes serious eye irritation.

Classification According to Directive 67/548/EEC or Directive 1999/45/EC

Toxic

Toxic by inhalation and if swallowed.

Harmful

Harmful in contact with skin.

Irritant

Irritating to the eyes.

Information concerning hazards for humans and the environment: Not applicable.37.0

Label Elements

Labeling according to EU guidelines: The product has been classified and marked following directives on hazardous materials.

Code letter and hazard designation of product: Toxic.

Risk phrases:

  • Harmful in contact with skin.
  • Toxic by inhalation and if ingested.
  • Irritating to the eyes.

Safety phrases:

  • Keep away from living quarters.
  • Wear suitable protective clothing, gloves, and eye/face protection.
  • In case of an accident or if you feel unwell, seek medical advice immediately (show the label where possible).
  • This material and its container must be disposed of as hazardous waste.

Classification System

 NFPA ratings (scale 0 – 4)

0

Health = 3

Fire = 0

Reactivity = 0

HMIS-ratings (scale 0 – 4)

HEALTH

FIRE

REACTIVITY

3

0

0

Health = 3

Fire = 0

Reactivity = 0

Other hazards

Results of PBT and vPvB assessment:

PBT: Not applicable.

vPvB: Not applicable.

 3. COMPOSITION AND INFORMATION ON INGREDIENTS

  • Chemical Characterization: Substances
  • Molecular Formula: C2H6O9U
  • Molecular Weight: 412.094
  • Appearance: Yellowish green crystalline color
  • Solubility: G anhydrous/100 g H2O: 0.45 (10°C), 0.50 (20°C), 3.16 (100°C)
  • Organic solvents: 0.0 %

4. FIRST AID MEASURES

General information:

  • Consult a doctor. Medical observation for at least 48 hours after the accident.
  • Immediately remove any clothing soiled by the product.
  • Symptoms of poisoning may even occur after several hours.
  • Remove the breathing apparatus only after contaminated clothing has been completely removed.
  • In case of irregular breathing or respiratory arrest provide artificial respiration.

After inhalation:

  • Supply fresh air or oxygen.
  • In case of unconsciousness, place the patient stably inside a position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.

After eye contact: Rinse the opened eye for several minutes under running water.

After ingesting: Do not induce vomiting.

5. FIREFIGHTING MEASURES

Extinguishing Media

Suitable extinguishing agents:

  • CO2, extinguishing powder, or water spray.
  • Fight larger fires with water spray or alcohol-resistant foam.

Special hazards arising from the substance or mixture: No further relevant information is available.

Advice for Firefighters

Protective equipment: Mouth respiratory protective device.

 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Not required.

Environmental precautions: Dilute with plenty of water.

Methods and material for containment and cleaning up:

  • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
  • Dispose of contaminated material as waste according to item 13.
  • Ensure adequate ventilation.

Reference to other sections:

  • See Section 7 for information on safe handling.
  • See Section 8 for information on personal protection equipment.
  • See Section 12 for disposal information.

7. HANDLING INFORMATION

Handling

Precautions for safe handling:

  • Ensure good ventilation and exhaustion at the workplace.
  • Open and handle the receptacle with care.
  • Prevent the formation of aerosols.

Information about protection against explosions and fires: Keep respiratory protective devices available.

Conditions for Safe Storage, Including Incompatibilities

Storage:

  • Requirements to be met by storerooms and receptacles: No special requirements.
  • Information about storage in one common storage facility: Not required.
  • Further information about storage conditions: Keep the receptacle tightly sealed.7.0
  • Specific end uses: No further relevant information is available.

Additional information about the design of technical systems: No further data; see item 7.

Control Parameters

Components with limit values that require monitoring at the workplace: Not required.

Additional information: The lists valid during the creation were used as a basis.

8. EXPOSURE CONTROLS

Personal Protective Equipment

At any detectable concentration: Any self-contained breathing apparatus with a full facepiece operated in a pressure-demand or other positive-pressure mode.
Any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure mode with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Escape – any air-purifying, full-facepiece respirator with a high-efficiency particulate filler.
Any appropriate escape-type, self-contained breathing apparatus.

General protective and hygienic measures:

  • Keep away from foodstuffs, beverages, and feed.
  • Immediately remove all soiled and contaminated clothing.
  • Wash hands before breaks and at the end of work.
  • Store protective clothing separately.
  • Avoid contact with the eyes.
  • Avoid contact with the eyes and skin.

Breathing equipment:

  • In case of brief exposure or low pollution use a respiratory filter device.
  • In case of intensive or longer exposure use an independent circulating air respiratory protective device.

Protection of hands:

  • Protective gloves:  The glove material must be impermeable and resistant to the product, the substance, and the preparation. Due to missing tests, no recommendation for the glove material can be given for the product, the preparation, and the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion, and the degradation
  • Material of gloves: The selection of suitable gloves does not depend on the material but also on further quality marks and varies from manufacturer to manufacturer.
  • Penetration time of glove material: The exact break-through time must be found by the manufacturer of the protective gloves and observed.

Eye protection: Tightly sealed goggles

Firefighting and Other Immediately Dangerous to Life or Health Conditions

Use any self-contained breathing apparatus with a full facepiece respirator and a high-efficiency particulate filter.

Use any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure modes with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure modes.

 9. STABILITY AND REACTIVITY

Chemical Stability

  • Thermal decomposition and conditions to be avoided: No decomposition if used according to specifications.
  • Possibility of hazardous reactions: No dangerous reactions are known.
  • Conditions to avoid: No further relevant information is available.
  • Incompatible materials: No further relevant information is available.
  • Hazardous decomposition products: No dangerous decomposition products are known.

11. INFORMATION ON TOXICOLOGICAL EFFECTS

Acute Toxicity

Primary irritant effect on the skin: No irritant effect.

on the eye: Irritating effect.

Sensitization: No sensitizing effects known.

12. WASTE TREATMENT METHODS

Recommendation:

  • Must not be disposed of together with household garbage.
  • Do not allow the product to reach the sewage system.

Uncleaned packaging:

Recommendation: Disposal must be made according to official regulations.

Recommended cleansing agent: Water, if necessary, with cleansing agents.

 13. TRANSPORTATION

UN-Number

DOT, ADR, IMDG, IATA: UN2910

UN Proper Shipping Name

DOT: Radioactive material, excepted package-limited quantity of material

ADR; 2910 Radioactive material, excepted package-limited quantity of material

IMDG, IATA: RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – LIMITED QUANTITY OF MATERIAL

Transport Hazard Classes

DOT, ADR, IMDG, IATA:

Class: 7 Radioactive material.

Packing Group

DOT, ADR, IMDG, IATA: II37.0

The classification of substances with multiple hazards must be determined following the criteria presented in the regulations mentioned above. Due to the various quantities and combinations of materials being shipped at one time, the information above must be determined based on the characteristics of the specific shipment.

Environmental Hazards

Marine pollutant: No

Special precautions for user warning: Radioactive material

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.

UN “Model Regulation”: UN2910, Radioactive material, excepted package-limited quantity of material, 7, II

Safety, health, and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): The substance is not listed.

Section 313 (Specific toxic chemical listings): Substance is not listed.

TSCA (Toxic Substances Control Act): Substance is listed.

Proposition 65

Chemicals known to cause cancer: Substance is not listed.

Chemicals known to cause reproductive toxicity for females: Substance is not listed.

Chemicals known to cause reproductive toxicity for males: Substance is not listed.

Chemicals known to cause developmental toxicity: Substance is not listed.

Carcinogenic Categories

EPA (Environmental Protection Agency): Substance is not listed.

TLV (Threshold Limit Value established by ACGIH): Substance is not listed.

NIOSH-Ca (National Institute for Occupational Safety and Health): Substance is not listed.

OSHA-Ca (Occupational Safety & Health Administration): Substance is not listed.

Product-Related Hazard Information

The product has been classified and marked following directives on hazardous materials 37.0

Hazard symbols: Toxic

Risk phrases:

  • Harmful in contact with skin.
  • Toxic by inhalation and if ingested.
  • Irritating to the eyes.

Safety phrases:

  • Keep away from living quarters.
  • Wear suitable protective clothing, gloves, eye, and face protection.
  • In case of an accident or if you feel unwell, seek medical advice immediately (show the label where possible).
  • This material and its container must be disposed of as hazardous waste.

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

Abbreviations and Acronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International

Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists

EINECS: European Inventory of Existing Commercial Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

14. OTHER INFORMATION

Copyright 2014 IBI Labs. License granted to make unlimited paper copies for internal use only.

IBI Labs requires that those who receive their materials comply with 29 CFR 1910.1200(h), which mandates that employers provide employees with effective information and training about hazardous chemicals in their workplace.

The contents of this document are believed to be accurate as of the date of revision and are provided in good faith. However, it is recommended that recipients use this information as supplementary and exercise caution and judgment regarding its accuracy and suitability. Please note that IBI Labs cannot be held responsible for any damage, direct or indirect, that occurs because of using the information provided in this Safety Data Sheet.

IBI Labs makes no warranties, expressed or implied, including warranties of merchantability and fitness for a particular purpose. This information is provided without warranty, and any use of the product that does not conform to this Safety Data Sheet, or that is used in combination with any other product or process, is the user’s responsibility.

Revision Date: 05/17/2024

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