1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Uranyl Nitrate Solution

Product Number: UN-1%

CAS RN: [13520-83-7]

Chemical Stability: Stable under recommended storage conditions.

Form: Liquid

Identified Uses: Laboratory chemicals, manufacture of substances.

Supplier

IBI Labs

3495 N. Dixie Hwy. Unit # 8

Boca Raton, FL 33431

Tel: 561-826-0061 Fax: 561-892-8450

Emergency Telephone Numbers

INFOTRAC

USA & Canada contact number: 1-800-535-5053

International contact number: 1-352-323-3500

2. HAZARDS IDENTIFICATION

Classification of The Substance or Mixture

GHS Classification in Accordance With 29 CFR 1910 (OSHA HCS):

Acute toxicity, Oral (Category 4), H302

For the full text of the H-Statements mentioned in this Section, see Section 16.

GHS Label Elements, Including Precautionary Statements

Pictogram

Signal word Warning

Hazard Statements

H302 Harmful if swallowed.

Precautionary Statements

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P330 Rinse mouth.

P501 Dispose of contents and container to an approved waste disposal plant.

Hazards Not Otherwise Classified (HNOC) or Not Covered by GHS: None.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures

Component Classification Concentration:

Bis(nitrato-O)dioxouranium hexahydrate

CAS-No. [13520-83-7]

EC-No. 233-266-3

Index-No. 092-002-00-3

Ox. Sol. 2; Acute Tox. 2;

STOT RE 2; Aquatic Acute 2;

Aquatic Chronic 2; H272,

H300 + H330, H373, H411

1 – 5 %

For the full text of the H-Statements mentioned in this Section, see section 16.

4. FIRST AID MEASURES

Description of First Aid Measures:

General Advice:

• Consult a physician.
• Show this safety data sheet to the doctor in attendance.
• Move out of dangerous areas.

Inhalation:

• If breathed in, move the person into fresh air.
• If not breathing, give artificial respiration.
• Consult a physician.

Skin Contact:

• Wash off with soap and plenty of water.
• Consult a physician.

Eye Contact: Flush eyes with water as a precaution.

Ingestion:

• Never give anything by mouth to an unconscious person.
• Rinse mouth with water.
• Consult a physician.

Most Important Symptoms and Effects, Both Acute and Delayed:

The most important known symptoms and effects are described in the labeling (see section 2 and in section 11).

Indication of Any Immediate Medical Attention and Special Treatment Needed: No Data Available.

5. FIREFIGHTING MEASURES

Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemicals, or carbon dioxide.

Special Hazards Arising from The Substance or Mixture: No Data Available.

Advice For Firefighters: Wear self-contained breathing apparatus for firefighting if necessary.

Further Information: No Data Available.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures:

• Use personal protective equipment.
• Avoid breathing vapors, mist, or gas. Ensure adequate ventilation.
• Evacuate personnel to safe areas.

For personal protection see section 8.

Environmental Precautions:

• Prevent further leakage or spillage if safe to do so.
• Do not let the product enter drains.

Methods and Materials for Containment and Cleaning Up:

• Soak up with inert absorbent material and dispose of as hazardous waste.
• Keep in suitable, closed containers for disposal.

Reference to Other Sections: For disposal see section 13.

7. HANDLING AND STORAGE

Precautions for Safe Handling:

• Avoid contact with skin and eyes.
• Avoid inhalation of vapor or mist.

For precautions see section 2.

Conditions for Safe Storage, Including Any safe storage, Including Incompatibilities:

• Keep the container tightly closed in a dry and well-ventilated place.
• Containers that are opened must be carefully resealed and kept upright to prevent leakage.
• Recommended storage temperature 2 – 8 °C

Specific End Use(s): Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Control Parameters

Components with workplace control parameters:

Component CAS-No. Value Control parameters

Basis Bis(nitrato-O)dioxouranium hexahydrate

13520-83-7 TWA 0.2 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Remarks Confirmed human carcinogen

TWA 0.05 mg/m3 USA. Occupational Exposure Limits

(OSHA) – Table Z-1 Limits for Air Contaminants TWA 0.05 ppm

USA. OSHA – TABLE Z-1 Limits for Air Contaminants – 1910.1000

STEL 0.6 mg/m3 USA. ACGIH Threshold Limit Values

(TLV)

Confirmed human carcinogen

Exposure Controls

Appropriate engineering controls:

• Handle following good industrial hygiene and safety practices.
• Wash hands before breaks and at the end of the workday.

Personal protective equipment

Eye and Face Protection:

• Face shield and safety glasses.
• Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin Protection:

• Handle with gloves.
• Gloves must be inspected before use.
• Use proper glove removal technique (without touching the glove’s outer surface) to avoid skin contact with this product.
• Dispose of contaminated gloves after use following applicable laws and good laboratory practices.
• Wash and dry hands.

Body Protection: Complete suit protecting against chemicals, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US), or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of Environmental Exposure:

• Prevent further leakage or spillage if safe to do so.
• Do not let the product enter drains.

At any detectable concentration:  Any self-contained breathing apparatus with a full facepiece operated in a pressure-demand or other positive-pressure mode.

Any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure mode with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.

Escape – any air-purifying, full-facepiece respirator with a high-efficiency particulate filler.

Any appropriate escape-type, self-contained breathing apparatus.

Firefighting and Other Immediately Dangerous to Life or Health Conditions

Use any self-contained breathing apparatus with a full facepiece respirator and a high-efficiency particulate filter.

Use any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure modes with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure modes.

9. TOXICOLOGICAL INFORMATION

Acute toxicity: No Data Available.

Inhalation: No Data Available.

Dermal: No Data Available.

Skin Corrosion/Irritation: No Data Available.

Serious Eye Damage or Irritation: No Data Available.

Respiratory or Skin Sensitization: No Data Available.

Germ Cell Mutagenicity: No Data Available.

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

Reproductive Toxicity: No Data Available.

Specific Target Organ Toxicity – Single Exposure: No Data Available.

Specific Target Organ Toxicity – Repeated Exposure: No Data Available.

Aspiration Hazard: No Data Available.

Additional Information

RTECS: No Data Available.

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated; kidney and liver injury may occur. Damage to the lungs, blood disorders, and symptoms may be delayed.

10. ECOLOGICAL INFORMATION

Toxicity: No Data Available.

Persistence and Degradability: No Data Available.

Bio-Accumulative Potential: No Data Available.

Mobility in Soil: No Data Available.

Results of PBT and vPvB Assessment: PBT/vPvB assessment not available as chemical safety assessment not required/not conducted.

Other Adverse Effects: No Data Available.

11. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Product:

• Contact a licensed professional waste disposal service to dispose of this material.
• Dissolve or mix the material with a combustible solvent and burn it in a chemical incinerator equipped with an afterburner and scrubber.
• Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated Packaging: Dispose of as an unused product.

12. TRANSPORT INFORMATION

DOT (US)

UN number: 2910

Class: 7

Proper Shipping Name: Radioactive material, excepted package-limited quantity of material (Bis(nitrato-O)dioxouranium hexahydrate)

Reportable Quantity (RQ): –

Marine pollutant: No

Poison Inhalation Hazard: No

IMDG

UN number: 2910

Class: 7 EMS-No: F-I, S-S

Proper Shipping Name: RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – LIMITED QUANTITY OF MATERIAL

(Bis(nitrato-O)dioxouranium hexahydrate)

Marine pollutant: No

IATA

UN number: 2910

Class: 7.4H

Proper Shipping Name: Radioactive material, excepted package – limited quantity of material (Bis(nitrato-O)dioxouranium hexahydrate.

Packing Group:

The classification of substances with multiple hazards must be determined following the criteria presented in the regulations mentioned above. Due to the various quantities and combinations of materials being shipped at one time, the information above must be determined based on the characteristics of the specific shipment.

13. REGULATORY INFORMATION

SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard.

Massachusetts Right to Know Components: Bis(nitrato-O)dioxouranium hexahydrate.

CAS-No. 13520-83-7 Revision Date 1994-04-01.

Pennsylvania Right to Know Components: Water CAS-No. 7732-18-5 Bis(nitrato-O)dioxouranium hexahydrate 13520-83-7 1994-04-01.

New Jersey Right to Know Components: Water CAS-No. 7732-18-5 Bis(nitrato-O)dioxouranium hexahydrate 13520-83-7 1994-04-01.

California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

14. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

Acute toxicity

Acute aquatic toxicity

Aquatic Chronic toxicity

H272 May intensify fire, oxidizer.

H300 + H330 Fatal if swallowed or if inhaled.

H302 Harmful if swallowed.

H373 May cause damage to organs through prolonged or repeated exposure.

H411 Toxic to aquatic life with long lasting effects.

Ox. Sol. Oxidizing solids.

STOT RE Specific target organ toxicity – repeated exposure.

HMIS Rating

Health hazard: 4

Chronic Health Hazard: *

Flammability: 0

Physical Hazard: 3

NFPA Rating

Health hazard: 4

Fire Hazard: 0

Reactivity Hazard: 0

Further Information

Copyright 2014 IBI Labs. License granted to make unlimited paper copies for internal use only.

IBI Labs requires that those who receive their materials comply with 29 CFR 1910.1200(h), which mandates that employers provide employees with effective information and training about hazardous chemicals in their workplace.

The contents of this document are believed to be accurate as of the date of revision and are provided in good faith. However, it is recommended that recipients use this information as supplementary and exercise caution and judgment regarding its accuracy and suitability. Please note that IBI Labs cannot be held responsible for any damage, direct or indirect, that occurs because of using the information provided in this Safety Data Sheet.

IBI Labs makes no warranties, expressed or implied, including warranties of merchantability and fitness for a particular purpose. This information is provided without warranty, and any use of the product that does not conform to this Safety Data Sheet, or that is used in combination with any other product or process, is the user’s responsibility.

Revision Date: 05/15/2024