1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: Uranyl Chloride Hydrated

Formula: UO2Cl2*3H2O

CAS RN: [13867-67-9]

Relevant identified uses of the substance or mixture and uses advised against Laboratory chemicals and manufacture of substances.

Supplier

IBI Labs

3495 N. Dixie Hwy. Unit # 8

Boca Raton, FL 33431

Tel: 561-826-0061 Fax: 561-892-8450

Emergency Telephone Numbers

INFOTRAC

USA & Canada contact number: 1-800-535-5053

International contact number: 1-352-323-3500

2. HAZARDS IDENTIFICATION

Classification of The Substance or Mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS):

Acute toxicity, Oral (Category 2), H300

Acute toxicity, Inhalation (Category 2), H330

Specific target organ toxicity – repeated exposure (Category 2), H373

Acute aquatic toxicity (Category 2), H401

Chronic aquatic toxicity (Category 2), H411

For the full text of the H-Statements mentioned in this Section, see Section 16.

GHS Label Elements, Including Precautionary Statements

Pictogram

Signal word: Danger

Hazard statements:

H300 + H330 Fatal if swallowed or if inhaled.

H373 May cause damage to organs through prolonged, or repeated exposure.

H411 Toxic to aquatic life with long lasting effects.

Precautionary statements:

P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P271 Use only outdoors, or in a well-ventilated area.

P273 Avoid release to the environment.

P284 Wear respiratory protection.

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/ physician.

P320 Specific treatment is urgent (see supplemental first aid instructions on this label).

P330 Rinse mouth.

P391 Collect spillage.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/ container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC) or not covered by GHS: Radioactive.

3. COMPOSITION AND INFORMATION ON INGREDIENTS, PHYSICAL AND CHEMICAL PROPERTIES

Molecular Weight: 394.979

Appearance: Yellow crystalline color

Component Classification Concentration

Uranyl Chloride Hydrated

Acute Tox. 2; STOT RE 2;

Aquatic Acute 2; Aquatic

Chronic 2; H300 + H330, H373, H411

For the full text of the H-Statements mentioned in this Section, see Section 15.

4. FIRST AID MEASURES

Description of First Aid Measures

General advice:

• Consult a physician.
• Show this safety data sheet to the doctor in attendance.
• Move out of dangerous areas.

If inhaled:

• If breathed in, move the person into fresh air.
• If not breathing, give artificial respiration.
• Consult a physician.

In case of skin contact:

• Wash off with soap and plenty of water.
• Take the patient immediately to the hospital.
• Consult a physician.

In case of eye contact:

• Flush eyes with water as a precaution.

If ingested:

• Never give anything by mouth to an unconscious person.
• Rinse mouth with water.
• Consult a physician.

Most important symptoms and effects,  acute and delayed: The most important known symptoms and effects are described in the labeling (see section 2 or in section 10).

Indication of any immediate medical attention and special treatment needed: No Data Available.

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemicals, or carbon dioxide.

Special hazards arising from the substance or mixture: Chlorides, Uranium oxides.

Firefighting and Other Immediately Dangerous to Life or Health Conditions

Use any self-contained breathing apparatus with a full facepiece respirator and a high-efficiency particulate filter.

Use any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure modes with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure modes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures:

• Wear respiratory protection.
• Avoid dust formation.
• Avoid breathing vapors, mist, or gas.
• Ensure adequate ventilation.
• Evacuate personnel to safe areas.
• Avoid breathing dust.

For personal protection see section 8.

Environmental precautions:

• Prevent further leakage or spillage if safe to do so.
• Do not let the product enter drains.
• Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:

• Pick up and arrange disposal without creating dust.
• Sweep up and shovel.
• Keep in suitable, closed containers for disposal.

Reference to other sections: For disposal see section 13.

7. HANDLING AND STORAGE

Precautions for safe handling:

• Avoid contact with skin and eyes and the formation of dust and aerosols.
• Provide appropriate exhaust ventilation at places where dust is formed.

Conditions for safe storage, including incompatibilities: Keep the container tightly closed in a dry and well-ventilated place.

Specific end uses: Apart from the uses mentioned in section 1.2, no other specific uses are stipulated.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Control Parameters

Components with workplace control parameters:

Component CAS-No. Value Control parameters

Uranyl Chloride

TWA 0.2 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Remarks Confirmed human carcinogen.

TWA 0.05 mg/m3 USA. Occupational Exposure Limits

(OSHA) – Table Z-1 Limits for Air Contaminants

TWA 0.05 ppm

USA. OSHA – TABLE Z-1 Limits for Air Contaminants – 1910.1000

STEL 0.6 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Confirmed human carcinogen.

TWA 0.05 mg/m3 USA. Occupational Exposure Limits

(OSHA) – Table Z-1 Limits for Air Contaminants

TWA 0.05 mg/m3 USA. OSHA – TABLE Z-1 Limits for Air Contaminants – 1910.1000

TWA 0.05 mg/m3 USA. NIOSH Recommended Exposure Limits

Potential Occupational Carcinogen

See Appendix A

Exposure Controls

Appropriate engineering controls:

• Avoid contact with skin, eyes, and clothing.
• Wash hands before breaks, and immediately after handling the product.

Personal Protective Equipment

At any detectable concentration: Any self-contained breathing apparatus with a full facepiece operated in a pressure-demand or other positive-pressure mode.

Any supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode or other positive-pressure mode with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.

Escape – any air-purifying, full-facepiece respirator with a high-efficiency particulate filler.

Any appropriate escape-type, self-contained breathing apparatus.

Eye and face protection:

• Face shield and safety glasses: Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:

• Handle with gloves.
• Gloves must be inspected before use.
• Use proper glove removal technique (without touching the glove’s outer surface) to avoid skin contact with this product.
• Dispose of contaminated gloves after use following applicable laws and good laboratory practices. Wash and dry hands.

Full contact:

• Material: Nitrile rubber.
• Minimum layer thickness: 0.11 mm.
• Break-through time: 480 min.
• Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M).

Splash contact:

• Material: Nitrile rubber.
• Minimum layer thickness: 0.11 mm.
• Break-through time: 480 min.
• Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M).
• Data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de.

Test method: EN374 If used in solution, or mixed with other substances, and under conditions that differ from EN 374, contact the supplier of the CE-approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering approval for any specific use scenario.

Body protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration, and amount of the dangerous substance at the specific workplace.

Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US), or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure:

• Prevent further leakage or spillage if safe to do so.
• Do not let the product enter drains.
• Discharge into the environment must be avoided.

9. STABILITY AND REACTIVITY

Chemical stability: Stable under recommended storage conditions.

Incompatible materials: Strong oxidizing agents.

Hazardous decomposition products:

• Other decomposition products: No Data Available.
• In the event of fire: See section 5.

10. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

LD50 Oral – rat – 204 mg/kg

Remarks:

• Behavioral tremor.
• Skin and Appendages.
• Other: Hair.
• Nutritional and Gross Metabolic: Changes in body temperature decrease.
• Dermal: No Data Available.

LD50 Subcutaneous – rat – 8.300 mg/kg.

Carcinogenicity:

Contains a radioactive isotope that may produce cancer and genetic mutation.

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known, or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen, or potential carcinogen by OSHA.

Reproductive Toxicity: May cause damage to organs through prolonged, or repeated exposure.

Additional Information

RTECS: No Data Available.

Conjunctivitis., Blood disorders, Symptoms may be delayed., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

11. ECOLOGICAL INFORMATION

Results of PBT and vPvB assessment: PBT/vPvB assessment not available as chemical safety assessment not required/not conducted.

Other adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long-lasting effects.

12. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Product:

• Offer surplus and non-recyclable solutions to a licensed disposal company.
• Contact a licensed professional waste disposal service to dispose of this material.
• Dissolve or mix the material with a combustible solvent and burn it in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging: Dispose of it as an unused product.

13. TRANSPORTATION

DOT (US)

UN number: 2910

Proper shipping name: Toxic solid, inorganic, n.o.s. (uranyl chloride)

Reportable Quantity (RQ): 100 lbs.

Marine pollutant: No

Poison Inhalation Hazard: No

IMDG

UN number: 2910 EMS-No: F-A, S-A

Proper shipping name: TOXIC SOLID, INORGANIC, N.O.S. (uranyl chloride)

Marine pollutant: Marine pollutant

IATA

UN number: 2910

Proper shipping name: Toxic solid, inorganic, n.o.s. (uranyl chloride).

Further Information

Radioactive material, excepted package – limited quantity of material.

Packing Group:

The classification of substances with multiple hazards must be determined following the criteria presented in the regulations mentioned above. Due to the various quantities and combinations of materials being shipped at one time, the information above must be determined based on the characteristics of the specific shipment.

14. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard.

Massachusetts Right to Know Components

Uranyl Chloride Hydrated

CAS-No.: 13867-67-9

Revision Date: 1993-04-24

Pennsylvania Right to Know Components

Uranyl Chloride Hydrated

New Jersey Right to Know Components

Uranyl Chloride Hydrated

CAS-No.: 13867-67-9

Revision Date: 1993-04-24

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

15. OTHER INFORMATION

Full Text of H-Statements Referred to Under Sections 2 and 3

Acute Tox. Acute toxicity.

Acute aquatic toxicity.

Chronic aquatic toxicity.

H300 Fatal if swallowed.

H300 + H330 Fatal if swallowed or if inhaled.

H330 Fatal if inhaled.

H373 May cause damage to organs through prolonged, or repeated exposure.

H401 Toxic to aquatic life.

HMIS Rating

Health hazard: 3

Chronic Health Hazard: *

Flammability: 0

Physical Hazard 0

NFPA Rating

Health hazard: 4

Fire Hazard: 0

Reactivity Hazard: 0

Further Information

Copyright 2014 IBI Labs. License granted to make unlimited paper copies for internal use only.

IBI Labs requires that those who receive their materials comply with 29 CFR 1910.1200(h), which mandates that employers provide employees with effective information and training about hazardous chemicals in their workplace.

The contents of this document are believed to be accurate as of the date of revision and are provided in good faith. However, it is recommended that recipients use this information as supplementary and exercise caution and judgment regarding its accuracy and suitability. Please note that IBI Labs cannot be held responsible for any damage, direct or indirect, that occurs because of using the information provided in this Safety Data Sheet.

IBI Labs makes no warranties, expressed or implied, including warranties of merchantability and fitness for a particular purpose. This information is provided without warranty, and any use of the product that does not conform to this Safety Data Sheet, or that is used in combination with any other product or process, is the user’s responsibility.

Revision Date: 05/07/2024