Uranyl Sodium Carbonate SDS

Safety Data Sheet

Print Date 12/20/2014

Revision Date 07/27/2021

1. PRODUCT AND COMPANY IDENTIFICATION

Product identifiers

Product Name: Uranyl Sodium Carbonate

Brand: IBI Labs

CAS-No.: 13021-32-4

Relevant identified uses of the substance or mixture and uses advised against

Identified Uses: Laboratory chemicals, Manufacture of substances.

Details of the supplier of the safety data sheet

Company IBI Labs

3495 N. Dixie Hwy. Unit # 8

Boca Raton, FL 33431 USA

Telephone: +1 561-826-0061

Fax: +1 561-892-8450

Emergency telephone number

Emergency Phone #: (561) 826-0061

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS):

Acute toxicity, Oral (Category 2), H300

Acute toxicity, Inhalation (Category 2), H330

Specific target organ toxicity – repeated exposure (Category 2), H373

Acute aquatic toxicity (Category 2), H401

Chronic aquatic toxicity (Category 2), H411

For the full text of the H-Statements mentioned in this section, see section 16.

GHS Label elements, including precautionary statements

Pictogram

 Uranyl
Sodium Carbonate MSDS

Signal word Danger

Hazard statements:

H300 + H330 Fatal if swallowed or if inhaled.

H373 May cause damage to organs through prolonged or repeated exposure.

H411 Toxic to aquatic life with long lasting effects.

Precautionary statements:

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink, or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P284 Wear respiratory protection.

P301 + P310 If Swallowed: Immediately call a Poison Center or a physician.

P304 + P340 If Inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P310 Immediately call a Poison Center or a physician.

P320 Specific treatment is urgent (see supplemental first aid instructions on this label).

P330 Rinse mouth.

P391 Collect spillage.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents and container to an approved waste disposal plant.

3. COMPOSITION & INFORMATION ON INGREDIENTS

Formula: UO2(CO3)*2NaCO3

Description: An odorless to chalky smelling orange-yellow sand-like solid in its pure crystalline form.

Formula Mass: 542 MW

Density: 5.6

4. HAZARDS AND PROTECTION

General advice:

  • Consult a physician.
  • Show this safety data sheet to the doctor in attendance.
  • Move out of dangerous area.

Storage:

  • Protect from physical damage.
  • Store at in cool, dry place.
  • Protect personnel from radiation emanation if present.
  • Separate from other readily oxidizable or combustible materials.

Handling:

  • All chemicals should be considered hazardous.
  • Avoid direct physical contact.
  • Use appropriate, approved safety equipment.
  • Untrained individuals should not handle this chemical or its container.
  • Handling should occur in a chemical fume hood.

Protection: Approved dust respirator self-contained breathing apparatus; goggles or face shield; protective clothing.

Respirators: Use NIOSH/MSHA approved respirator appropriate for exposure of concern.

Small spills and leaks:

  • Evacuate area and ventilate.
  • Wear protective equipment.
  • If required, use an inert absorbent.
  • Sweep up and place in an appropriate container for disposal.
  • Wash contaminated surfaces.

Stability: No data available.

Incompatibilities:

  • Can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers).
  • Can react violently with active metals, cyanides, esters, and thiocyanates.

5. FIREFIGHTING

Extinguishing media

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.

Special hazards arising from the substance or mixture: Carbon oxides, Uranium oxides.

Advice for firefighters:

  • Wear self-contained breathing apparatus for firefighting if necessary.
  • Contain runoff.

6. HEALTH

Exposure Limits

OSHA: PEL (8 h TWA): 0.05 mg

Exposure Effects: Supra lethal radiation doses may result in headache, acute brain syndrome, alterations in mental status including coma, and (rarely) seizures within minutes of exposure. Prenatal ionizing radiation exposure may cause
congenital anomalies, mental retardation, and an increased incidence of seizures.

Ingestion: Gastrointestinal syndrome (nausea/vomiting) commonly occurs after doses of 9 to 20 gy and may occur following doses as low as 5 gy. Initial vomiting is followed by persistent diarrhea, which may be bloody.

Inhalation: Pulmonary radiation injury may result in radiation pneumonitis and radiation pulmonary fibrosis.

Skin: Thermonuclear burns may occur. If erythema is produced by a penetrating radiation, serious systemic injury is certain.

First Aid

Ingestion:

  • Seek medical attention.
  • If individual is drowsy or unconscious, do not give anything by mouth, place individual on the left side with the head down.
  • Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting.
  • If possible, do not leave individual unattended.

Inhalation:

  • Monitoring exposed patients for contamination and decontamination procedures should be started.
  • All personnel involved in handling patients should wear disposable protective clothing.
  • The patient should be completely undressed and given a soap and water bath or shower (if the patient’s
    condition permits and if the facility exists).
  • Acute inhalation of radionuclides presents some difficult problems.

Skin:

  • Remove contaminated clothing.
  • Wash exposed area with soap and water.
  • If symptoms persist, seek medical attention.
  • Launder clothing before reuse.

Eyes:

  • If symptoms develop, immediately move individual away from exposure and into fresh air.
  • Flush eyes gently with water for at least 15 minutes while holding eyelids apart.
  • Seek immediate medical attention.

7. TRANSPORTATION

USCG CHRIS code: URS

Systematic name: Uranium Sodium Carbonate

Other names: Uranyl Sodium Carbonate

Molecular formula: UO2(CO3)*2NaCO3

Molar mass: 542 g/mol

The U.S. Department of Transportation (D.O.T.) Code of Federal Regulations (49 CFR Parts 100-185), the International Air Transportation Association (IATA), International Civil Aviation Organization (ICAO), and International Maritime Organization (IMDG) are all factored into the classification and transport of material.

Proper Shipping Name:

Hazard Class:

UN/ID Number:                                          To be determined on a case-by-case basis.

Special Information:

Packing Group:

Classification of substances with multiple hazards must be determined in accordance with the criteria presented in regulations mentioned above. Due to the various quantities/combinations of materials being shipped at one time, the information above must be determined based on the characteristics of the specific shipment.

8. ECOLOGICAL INFORMATION

Toxicity: No data available.

Persistence and degradability: No data available.

Bio-accumulative potential: No data available.

Mobility in soil: No data available.

Results of PBT and vPvB assessment: PBT/vPvB assessment not available as chemical safety assessment not required/not conducted.

Other adverse effects

  • An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
  • Toxic to aquatic life with long lasting effects.
  • No data available.

9. DISCLAIMER AND REFERENCES

Uranium like other actinides readily forms a dioxide uranyl core (UO2). In the environment, this uranyl core readily
complexes with carbonate to form charged complexes. Although uranium forms insoluble solids or adsorbs to mineral surfaces at alkaline pH it is these soluble carbonate complexes that increase its solubility, availability, and mobility with low affinities to soil. Uranium(VI) generally forms a pH-dependent suite of uranyl-carbonate complexes in ground water solutions:

  • UO2(OH)2+1
  • UO2(CO3)2-2
  • UO2(CO3)3-4
  • UO2(CO3)(OH)3-1

A common method for concentrating uranium from a solution uses solutions of uranyl carbonates which are passed through a resin bed where the complex ions are transferred to the resin by ion exchange with a negative ion-like chloride. After buildup of the uranium complex on the resin, the uranium is eluted with a salt solution and the uranium is precipitated in another process.

10. FURTHER INFORMAITON

Copyright 2014 IBI Labs. License granted to make unlimited paper copies for internal use only.

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product regarding to appropriate safety precautions. It does not represent any guarantee of the properties of the product. IBI Labs and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product

Preparation Information

IBI Labs

Product Safety – Americas Region

1-561-826-0061

Revision Date: 07/27/2021

Print Date: 12/20/2014

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